Organic-chemistry-II All Unit Notes
BPharmacy, 3rd Semester, Notes
Free PDF Download
Content:
UNIT I: Benzene and its derivatives
Analytical, synthetic and other evidences in the derivation of structure
of benzene, Orbital picture, resonance in benzene, aromatic
characters, Huckel’s rule
Reactions of benzene - nitration, sulphonation, halogenationreactivity, Friedelcrafts alkylation- reactivity, limitations,
Friedelcrafts acylation.
Substituents, effect of substituents on reactivity and orientation of
mono substituted benzene compounds towards electrophilic
substitution reaction
Structure and uses of DDT, Saccharin, BHC and Chloramine
UNIT II: Phenols, Aromatic Amines
Phenols: Acidity of phenols, effect of substituents on acidity, qualitative
tests, Structure and uses of phenol, cresols, resorcinol, naphthols
Aromatic Amines: Basicity of amines, effect of substituents on basicity,
and synthetic uses of aryl diazonium salts
UNIT III: Fats and Oils
Fatty acids – reactions.
Hydrolysis, Hydrogenation, Saponification and Rancidity of oils, Drying
oils
Analytical constants – Acid value, Saponification value, Ester value,
Iodine value, Acetyl value, Reichert Meissl (RM) value – significance and
principle involved in their determination.
UNIT IV: Polynuclear hydrocarbons
Synthesis, reactions, Structure and medicinal uses of Naphthalene, Phenanthrene, Anthracene,
Diphenylmethane, Triphenylmethane and their derivatives
UNIT V: Cycloalkanes
Stabilities – Baeyer’s strain theory, limitation of Baeyer’s strain theory,
Coulson and Moffitt’s modification, Sachse Mohr’s theory (Theory of
strainless rings), reactions of cyclopropane and cyclobutane only
UNIT VI: Polycyclic Aromatic Hydrocarbons
UNIT I: Benzene and its derivatives
UNIT II: Phenols, Aromatic Amines
UNIT III: Fats and Oils
UNIT IV: Polynuclear hydrocarbons
UNIT V: Cycloalkanes
UNIT VI: Polycyclic Aromatic Hydrocarbons
Post a Comment
0 Comments